Equilibrium and Kinetics Adsorption of Disperse Blue 56 on White Jute Fiber
Abstract
In this research, the adsorption of disperse blue 56 from aqueous solutions by white jute fiber as an adsorbent was studied. Batch experiments were performed as a function of adsorbent dosage, pH, contact time and initial dye concentration. The optimum conditions for the adsorption of disperse blue 56 were an adsorbent dosage of 1.0 g and a pH of 6. The adsorption equilibrium was achieved within 240 min of contact time. It was found that the adsorption capacity increased with increasing initial dye concentration. The Langmuir and Freundlich isotherms were adopted in the analysis of the equilibrium adsorption data. The adsorption isotherm of white jute fiber was well fitted with the Langmuir isotherm which was based on the monolayer adsorption model. The maximum adsorption capacity of white jute fiber was found to be 3.87 mg/g. The adsorption kinetics were analyzed using the pseudo-first order and pseudo-second order kinetic models. The experimental data were fitted well to the pseudo-second order kinetic model. Keywords : white jute fiber ; disperse blue 56 ; adsorption, isotherm, kineticReferences
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56 and disperse red 135 dye from aqueous dispersions by modified montmorillonite nano clay. Chemical Industry and Chemical Engineering Quarterly, 23(1), 21-29.
Ahmed, A. S., Islam, M. S., Hassan, A., Haafiz, M. K. M., Islam, K. N., & Arjmandi, R. (2014). Impact of succinic
anhydride on the properties of jute fiber/polypropylene biocomposites. Fibers and Polymers, 15(2), 307-314.
Assawasaengrat, P., & Clowutimon, W. (2010). Adsorption of dyes by natural adsorbents. Ladkrabang
Engineering Journal, 27(4), 61-66. (in Thai)
Begum, H. A., Howlader, M. R., Siddique, A. B., & Khan, A. N. (2017). Investigation of functional properties
changing in different chemical treatments of various cellulosic fibers using FTIR. Saudi Journal of Engineering and Technology, 2(7), 280-285.
Chooaksorn, W. (2012). Color removal technology in industrial wastewater. Burapha Science Journal, 17(1),
181-191. (in Thai)
Duan, L., Yu, W., & Li, Z. (2017). Analysis of structural changes in jute fibers after peracetic acid treatment.
Journal of Engineered Fibers and Fabrics, 12(1), 33-42.
Faust, S. D., & Aly, O. M. (1987). Adsorption Processes for Water Treatment. Boston: Butterworths Publishers.
Gupta, V.K., & Suhas. (2009). Application of low-cost adsorbents for dye removal - A review. Journal of
Environmental Management, 90(8), 2313-2342.
Isa, M. H., Lang, L. S., Asaari, F. A.H., Aziz, H. A., Ramli, N. A., & Dhas, J. P. A. (2007). Low cost removal of
disperse dyes from aqueous solution using palm ash. Dyes and Pigments, 74(2), 446-453.
Kılıç, M., & Janabi, A. S. K. (2017). Investigation of dyes adsorption with activated carbon obtained from
Cordia myxa. Bilge International Journal of Science and Technology Research, 1(2), 87-104.
Mays, T.J. (2007). A new classification of pore sizes. Studies in Surface Science and Catalysis, 160, 57-62.
Noureddine, B., Samir, Q., Ali, A., Abederrahman, N., & Yhya, A. (2008). Adsorption of disperse blue SBL dye by
synthesized poorly crystalline hydroxyapatite. Journal of Environmental Sciences, 20(10), 1268-1272.
Özacar, M., & Şengil, İ. A. (2004). Application of kinetic models to the sorption of disperse dyes onto alunite.
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 242(1-3), 105-113.
Özacar, M., & Şengil, İ. A. (2004). Equilibrium data and process design for adsorption of disperse dyes onto
Alunite. Environmental Geology, 45, 762-768.
Paiyarat, J. (2016). Removal of basic dye and reactive dye using activated sludge (Master’s thesis).
Chulalongkorn University, Bangkok. (in Thai)
Phijarn, J., Punchon, W., Kanna, M., Somnam, S., & Wongnawa, S. (2015). Decolorization of mixed dyes
(methylene blue and methyl orange) in aqueous solution by photo-fenton process. Burapha Science Journal, 20(1), 174-185. (in Thai)
Rungrojchaipon, P. (2011). Porous materials. Journal of Science Ladkrabang, 20(1), 60-69. (in Thai)
Sangarunlert, W. (2015). Adsorption of methyl red dye by activated carbon from egg shell and ark shell by
chemical activation method. Science and Technology Nakhon Sawan Rajabhat University Journal, 7(7), 97-110. (in Thai)
Sansunon, P., En-Oon, P., & Piyamongkala, K. (2013). Kinetics and mechanism adsorption of direct red 80
dye by modifed bagasse. In Proceedings of 51st Kasetsart University Annual Conference.
(pp. 189-196). Bangkok: Kasetsart University. (in Thai)
Silva, I. L. A., Bevitori, A. B., Rohen, L. A., Margem, F. M., Braga, F. O., & Monteiro, S. N. (2016). Characterization
by fourier transform infrared (FTIR) analysis for natural jute fiber. Materials Science Forum, 869,
283-287.
Srimoon, R., & Kanavong, V. (2014). Decolourization efficiency of rambutan coal modified with wood vinegar.
Rajamangala University of Technology Tawan-ok Research Journal, 7(1), 31-37. (in Thai)
Srimoon, R. (2016). Dyes treatment in wastewater using adsorption processes. KKU Science Journal, 44(3),
419-434. (in Thai)
Sukpreabprom, H., Arquero, O. A., Naksata, W., Sooksamiti, P., & Janhom, S. (2014). Isotherm, kinetic and
thermodynamic studies on the adsorption of Cd(II) and Zn(II) ions from aqueous solutions onto bottom ash. International Journal of Environmental Science and Development, 5(2), 165-170.
Suttanan, R., & Piyamongkala, K. (2011). Kinetic and thermodynamic adsorption of methylene blue by modified
rice husk. The Journal of King Mongkut's University of Technology North Bangkok, 21(2), 337-348. (in Thai)
Tipboonsri, P. (2018). Forming continuous composite materials from polypropylene fibers reinforced by jute
fibers by pultrusion process (Master’s thesis). Rajamangala University of Technology Thanyaburi, Pathumthani. (in Thai)
Umpuch, C., Khumphu, T., Thongfuang, N., Kaewsiri, S., Paopo, I., Sangthean, T., & Sangthean, P. (2017).
Adsorption of reactive black 5 dye on activated carbon prepared from water hyacinth. Journal of Science and Technology, Ubon Ratchathani University, 19(1), 163-177. (in Thai)
Uthaiku, A. (2018). The Study of Chemical Composition and Preparation of film Cellulose from Cattail (Typha
angustifolia L.) in Saline Soil (Master’s thesis). Rajabhat Maha Sarakham University, Maha Sarakham. (in Thai)
Zenasni, M. A., Benfarhi, S., Merlin, A., Molina, S., George, B., & Meroufel, B. (2012). Adsorption of Cu(II) on
maghnite from aqueous solution: Effects of pH, initial concentration, interaction time and temperature. Natural Science, 4(11), 856-868.
56 and disperse red 135 dye from aqueous dispersions by modified montmorillonite nano clay. Chemical Industry and Chemical Engineering Quarterly, 23(1), 21-29.
Ahmed, A. S., Islam, M. S., Hassan, A., Haafiz, M. K. M., Islam, K. N., & Arjmandi, R. (2014). Impact of succinic
anhydride on the properties of jute fiber/polypropylene biocomposites. Fibers and Polymers, 15(2), 307-314.
Assawasaengrat, P., & Clowutimon, W. (2010). Adsorption of dyes by natural adsorbents. Ladkrabang
Engineering Journal, 27(4), 61-66. (in Thai)
Begum, H. A., Howlader, M. R., Siddique, A. B., & Khan, A. N. (2017). Investigation of functional properties
changing in different chemical treatments of various cellulosic fibers using FTIR. Saudi Journal of Engineering and Technology, 2(7), 280-285.
Chooaksorn, W. (2012). Color removal technology in industrial wastewater. Burapha Science Journal, 17(1),
181-191. (in Thai)
Duan, L., Yu, W., & Li, Z. (2017). Analysis of structural changes in jute fibers after peracetic acid treatment.
Journal of Engineered Fibers and Fabrics, 12(1), 33-42.
Faust, S. D., & Aly, O. M. (1987). Adsorption Processes for Water Treatment. Boston: Butterworths Publishers.
Gupta, V.K., & Suhas. (2009). Application of low-cost adsorbents for dye removal - A review. Journal of
Environmental Management, 90(8), 2313-2342.
Isa, M. H., Lang, L. S., Asaari, F. A.H., Aziz, H. A., Ramli, N. A., & Dhas, J. P. A. (2007). Low cost removal of
disperse dyes from aqueous solution using palm ash. Dyes and Pigments, 74(2), 446-453.
Kılıç, M., & Janabi, A. S. K. (2017). Investigation of dyes adsorption with activated carbon obtained from
Cordia myxa. Bilge International Journal of Science and Technology Research, 1(2), 87-104.
Mays, T.J. (2007). A new classification of pore sizes. Studies in Surface Science and Catalysis, 160, 57-62.
Noureddine, B., Samir, Q., Ali, A., Abederrahman, N., & Yhya, A. (2008). Adsorption of disperse blue SBL dye by
synthesized poorly crystalline hydroxyapatite. Journal of Environmental Sciences, 20(10), 1268-1272.
Özacar, M., & Şengil, İ. A. (2004). Application of kinetic models to the sorption of disperse dyes onto alunite.
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 242(1-3), 105-113.
Özacar, M., & Şengil, İ. A. (2004). Equilibrium data and process design for adsorption of disperse dyes onto
Alunite. Environmental Geology, 45, 762-768.
Paiyarat, J. (2016). Removal of basic dye and reactive dye using activated sludge (Master’s thesis).
Chulalongkorn University, Bangkok. (in Thai)
Phijarn, J., Punchon, W., Kanna, M., Somnam, S., & Wongnawa, S. (2015). Decolorization of mixed dyes
(methylene blue and methyl orange) in aqueous solution by photo-fenton process. Burapha Science Journal, 20(1), 174-185. (in Thai)
Rungrojchaipon, P. (2011). Porous materials. Journal of Science Ladkrabang, 20(1), 60-69. (in Thai)
Sangarunlert, W. (2015). Adsorption of methyl red dye by activated carbon from egg shell and ark shell by
chemical activation method. Science and Technology Nakhon Sawan Rajabhat University Journal, 7(7), 97-110. (in Thai)
Sansunon, P., En-Oon, P., & Piyamongkala, K. (2013). Kinetics and mechanism adsorption of direct red 80
dye by modifed bagasse. In Proceedings of 51st Kasetsart University Annual Conference.
(pp. 189-196). Bangkok: Kasetsart University. (in Thai)
Silva, I. L. A., Bevitori, A. B., Rohen, L. A., Margem, F. M., Braga, F. O., & Monteiro, S. N. (2016). Characterization
by fourier transform infrared (FTIR) analysis for natural jute fiber. Materials Science Forum, 869,
283-287.
Srimoon, R., & Kanavong, V. (2014). Decolourization efficiency of rambutan coal modified with wood vinegar.
Rajamangala University of Technology Tawan-ok Research Journal, 7(1), 31-37. (in Thai)
Srimoon, R. (2016). Dyes treatment in wastewater using adsorption processes. KKU Science Journal, 44(3),
419-434. (in Thai)
Sukpreabprom, H., Arquero, O. A., Naksata, W., Sooksamiti, P., & Janhom, S. (2014). Isotherm, kinetic and
thermodynamic studies on the adsorption of Cd(II) and Zn(II) ions from aqueous solutions onto bottom ash. International Journal of Environmental Science and Development, 5(2), 165-170.
Suttanan, R., & Piyamongkala, K. (2011). Kinetic and thermodynamic adsorption of methylene blue by modified
rice husk. The Journal of King Mongkut's University of Technology North Bangkok, 21(2), 337-348. (in Thai)
Tipboonsri, P. (2018). Forming continuous composite materials from polypropylene fibers reinforced by jute
fibers by pultrusion process (Master’s thesis). Rajamangala University of Technology Thanyaburi, Pathumthani. (in Thai)
Umpuch, C., Khumphu, T., Thongfuang, N., Kaewsiri, S., Paopo, I., Sangthean, T., & Sangthean, P. (2017).
Adsorption of reactive black 5 dye on activated carbon prepared from water hyacinth. Journal of Science and Technology, Ubon Ratchathani University, 19(1), 163-177. (in Thai)
Uthaiku, A. (2018). The Study of Chemical Composition and Preparation of film Cellulose from Cattail (Typha
angustifolia L.) in Saline Soil (Master’s thesis). Rajabhat Maha Sarakham University, Maha Sarakham. (in Thai)
Zenasni, M. A., Benfarhi, S., Merlin, A., Molina, S., George, B., & Meroufel, B. (2012). Adsorption of Cu(II) on
maghnite from aqueous solution: Effects of pH, initial concentration, interaction time and temperature. Natural Science, 4(11), 856-868.
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2021-05-05
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