Determination of Surface Tension by Pendant Drop Method: Effect of Tip’s Diameters
Abstract
This research aims design for the experimental setup to determine surface tension of liquids by the pendant drop method. This experiment was designed for student in the upper secondary level or higher education. Photographs of water droplet were taken, and Young-Laplace equation was applied. The setup consists of a syringe with its tip straight cut for diameters of 0.60, 0.80 and 1.2 mm. A lamp and smartphone were set to take photographs which are analyzed by ImgaeJ program. A drop of distilled water was formed at the tip. The pendant drop method requires measuring diameter. The value of the diameter of the drop at its widest part was DE and the value of the diameter of in a position at vertical distance DE from the lowest end was DS. From the results, the diameter of the dropper's tip does not affect the surface tension of the distilled water. But the shape of the water drop affects to the surface tension. The difference between DE and DS of the water drops from various tip's diameters should be in the range of 0.080 – 0.10 mm. In order to obtain accurate surface tension, the water drop must maintain its shape before it leaves the tip of the dropper that the balance between surface tension and the gravitational force. Finally, the tip's diameter of dropper and the volume of distilled water do not affect the surface tension. Keywords : Surface tension, Pendant drop method, Young Laplace’s equationReferences
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Physical Chemistry, 42(8), 1001–1019.
Concetto, G. (2006). Measurement of surface tension by the dripping from a needle. Physics Education, 41(5),
440-444.
Chen, H., Muros-Cobos, J.L., Holgado-Terriza, J.A., and Amirfazli, A. (2017). Surface tension measurement with a smartphone using a pendant drop. Colloids and Surface A Physicochemical and Engineering
Aspects, 533, 213-217.
Goncalves, F.A., Kestin, J., and Sengers, J.V. (1991). Surface-Tension Effects in Suspended-Level Capillary
Viscometers, International Journal of Thermophysics, 12, 1013-1028.
Joseph, D.B., Michael J. N., Raymond R.D., Derek, Y.C.C., and Rico, F. T. (2015). Measurement of surface and
interfacial tension using pedant drop tensiometry. Journal of Colloid and Interface Science, 454, 226-
237.
Michael, O., and Kornelia, A. (1998). Correlation between surface tension and physical paint properties. Progress
in organic coatings, 33(3-4), 197-201.
Nicolas-Alexandre, G., Zakari, D., Maxime, L., Adrian, G., Nicolas, D., Antoine, D., and Ulysse, D. (2017). Surface
tension measurements with a smartphone. Physics Teacher, 55, 498 - 499.
Rudolph, M. (1935). Surface Tension by the ring method: applicability of the Du Nouy apparatus. Journal of Chemical Education, 12, 573-576.
Stauffer C.E., (1965). The measurement of surface tension by the pendant drop technique. The Journal of
Physical Chemistry, 69(6), 1933-1938.
Tomas, K., Frederic, D., and Andree, V. (2007). Importance of surface tension characterization for food
pharmaceutical and packaging products. Critical Reviews in Food Science and Nutrition, 46, 391- 407.
sciences. Journal of pharmacy and pharmaceutical sciences, 12(2), 218-228.
Andreas, J. M., Hauser, E. A., and Tucker, W.B. (1937). Boundary tension by pendant drops. The Journal of
Physical Chemistry, 42(8), 1001–1019.
Concetto, G. (2006). Measurement of surface tension by the dripping from a needle. Physics Education, 41(5),
440-444.
Chen, H., Muros-Cobos, J.L., Holgado-Terriza, J.A., and Amirfazli, A. (2017). Surface tension measurement with a smartphone using a pendant drop. Colloids and Surface A Physicochemical and Engineering
Aspects, 533, 213-217.
Goncalves, F.A., Kestin, J., and Sengers, J.V. (1991). Surface-Tension Effects in Suspended-Level Capillary
Viscometers, International Journal of Thermophysics, 12, 1013-1028.
Joseph, D.B., Michael J. N., Raymond R.D., Derek, Y.C.C., and Rico, F. T. (2015). Measurement of surface and
interfacial tension using pedant drop tensiometry. Journal of Colloid and Interface Science, 454, 226-
237.
Michael, O., and Kornelia, A. (1998). Correlation between surface tension and physical paint properties. Progress
in organic coatings, 33(3-4), 197-201.
Nicolas-Alexandre, G., Zakari, D., Maxime, L., Adrian, G., Nicolas, D., Antoine, D., and Ulysse, D. (2017). Surface
tension measurements with a smartphone. Physics Teacher, 55, 498 - 499.
Rudolph, M. (1935). Surface Tension by the ring method: applicability of the Du Nouy apparatus. Journal of Chemical Education, 12, 573-576.
Stauffer C.E., (1965). The measurement of surface tension by the pendant drop technique. The Journal of
Physical Chemistry, 69(6), 1933-1938.
Tomas, K., Frederic, D., and Andree, V. (2007). Importance of surface tension characterization for food
pharmaceutical and packaging products. Critical Reviews in Food Science and Nutrition, 46, 391- 407.
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Published
2022-09-08
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