Naked-Eye Test Kit for Copper (II) Ion Using Cellulose Triacetate as Solid Support
Abstract
A new rhodamine B optical chemosensor (L) was synthesized and employed for the naked-eye test kit for copper (II) ion using cellulose triacetate as solid support. L was obtained as pale pink solid in 81%. The naked-eye test kit which is a colorless film was prepared. In the presence of Cu2+, the color of the test kit was changed from colorless to pink. This is due to the ring opening spirolactam in L which induced by Cu2+ giving CuL complex. In the optimum conditions, the test kit showed a linear concentration range between 0.05 and 4.0 ppm Cu2+.The detection limit and limit of quantitation of Cu2+ by the sensing membrane L-CTA are calculated to be 0.6 ppm and 2.0 ppm, respectively. Keywords : rhodamine B optical chemosensor ; cellulose triacetate as solid support ; naked-eye test kit for copper (II) ion ; spirolactam ring openingReferences
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Chen, Y., Chen, B., Han, Y. (2016). A Novel Rhodamine-based Fluorescent Probe for the Fluorogenic and Chromogenic Detection of Pd2+ Ions and Its Application in Live-cell Imaging. Sensors and Actuators B: Chemical, 237, 1-7.
Choi, Y. W., Lee, J. J., You, G. R, Lee, S. Y. & Kim, C. (2015). Chromogenic Naked-eye Detection of Copper ion and Fluoride. RSC Advance, 5, 86463-86472.
Han, S. O., Son, W. K., Youk, J. H., Lee, T. S. & Park, W. H. (2005). Ultrafine Porous Fibers Electrospun from Cellulose Triacetate. Materials Letters, 59, 2998-3001.
Kumawat, L. K., Mergu, N., Singh, A. K. & Gupta, V. K. (2015). A novel Optical Sensor for Copper Ions Based on Phthalocyanine Tetrasulfonic Acid. Sensors and Actuators B: Chemical, 212, 389-394.
Levi, S. & Purdy, W. C. (1980). The AAS Determination of Copper and Zinc Levels in the Serum of Hemodialysis Patients. Clinical Biochemistry, 19, 253-258.
Pang, F. M., Teng, S. P., Teng, T. T. & Omar, A. K. M. (2009). Heavy Metals Removal by Hydroxide Precipitation and CoagulationFlocculation Methods from Aqueous Solutions. Water Quality Research Journal of Canada, 44, 1-9.
Rotondo, E., Pietropaolo, R., Tresoldi, G., Faraone, F. & Cusmano, F. (1976). Mechanism of Formation of Schiff base Complexes. Part. I. Reaction of Ni(bis-salicylaldehyde) with Primary Amines. Inorganica Chimica Acta, 17, 181-191.
Rouis, A., Darbost, U., Bonnamour, I. & Ouada, H.B. (2015). Development and Characterization of a Copper Ion-selective Optical Sensor Based on a Novel Calix[4]dicyano-diimidazole Thin Film. Materials Chemistry and Physics, 164, 145-149.
Santos, É. J., Herrmann, A. B., Olkuszewski, J. L., Pierre, T. D. S. & Curtius, A. J. (2005). Determination of Trace Metals in Electrolytic Copper by ICP-OES and ICP-MS. Brazilian Archives of Biology and Technology, 48, 681-687.
Strausak, D., Mercer, J. F. B., Dieter, H. H., Stremmel, W. & Multhaup, G. (2001). Copper in Disorders with Neurological Symptoms: Alzheimer’s, Menkes, and Wilson diseases. Brain Research Bulletin, 55,
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Wang, J., Yang, Q., Song, H. & Zhang, W. (2012). A Fluorescent Probe of N′-formyl-rhodamine B Hydrazide: Structure and Spectral Properties of Protonation Behaviour. Organic & Biomolecular Chemistry, 10,
7677-7680.
Xiang, Y., Tong, A., Jin, P., Ju, Y. (2006). New Fluorescent Rhodamine Hydrazone Chemosensor for Cu(II) with High Selectivity and Sensitivity. Organic Letters, 8, 2863-2866.
Zhang, L.-Z. (2013). Conjugate Heat and Mass Transfer in Heat Mass Exchanger Ducts: Chapter 12 - Novel Materials for Heat and Mass Exchangers. Novel Materials for Heat and Mass Exchangers, 335-369.
Baslaka, C. & Kursunlu, A. N. (2018). A Naked-eye Fluorescent Sensor for Copper(ii) Ions Based on a Naphthalene Conjugate Bodipy Dye. Photochemical & Photobiological Sciences, 17, 1091-1097.
Chamjangali, M. A., Soltanpanah, S., & Goudarzi, N. (2009). Development and Characterization of a Copper Optical Sensor Based on Immobilization of Synthesized 1-phenyl-1,2-propanedione-2-oxime thiosemicarbazone on a Triacetylcellulose Membrane. Sensors and Actuators B: Chemical, 138(1),
251-256.
Chen, Y., Chen, B., Han, Y. (2016). A Novel Rhodamine-based Fluorescent Probe for the Fluorogenic and Chromogenic Detection of Pd2+ Ions and Its Application in Live-cell Imaging. Sensors and Actuators B: Chemical, 237, 1-7.
Choi, Y. W., Lee, J. J., You, G. R, Lee, S. Y. & Kim, C. (2015). Chromogenic Naked-eye Detection of Copper ion and Fluoride. RSC Advance, 5, 86463-86472.
Han, S. O., Son, W. K., Youk, J. H., Lee, T. S. & Park, W. H. (2005). Ultrafine Porous Fibers Electrospun from Cellulose Triacetate. Materials Letters, 59, 2998-3001.
Kumawat, L. K., Mergu, N., Singh, A. K. & Gupta, V. K. (2015). A novel Optical Sensor for Copper Ions Based on Phthalocyanine Tetrasulfonic Acid. Sensors and Actuators B: Chemical, 212, 389-394.
Levi, S. & Purdy, W. C. (1980). The AAS Determination of Copper and Zinc Levels in the Serum of Hemodialysis Patients. Clinical Biochemistry, 19, 253-258.
Pang, F. M., Teng, S. P., Teng, T. T. & Omar, A. K. M. (2009). Heavy Metals Removal by Hydroxide Precipitation and CoagulationFlocculation Methods from Aqueous Solutions. Water Quality Research Journal of Canada, 44, 1-9.
Rotondo, E., Pietropaolo, R., Tresoldi, G., Faraone, F. & Cusmano, F. (1976). Mechanism of Formation of Schiff base Complexes. Part. I. Reaction of Ni(bis-salicylaldehyde) with Primary Amines. Inorganica Chimica Acta, 17, 181-191.
Rouis, A., Darbost, U., Bonnamour, I. & Ouada, H.B. (2015). Development and Characterization of a Copper Ion-selective Optical Sensor Based on a Novel Calix[4]dicyano-diimidazole Thin Film. Materials Chemistry and Physics, 164, 145-149.
Santos, É. J., Herrmann, A. B., Olkuszewski, J. L., Pierre, T. D. S. & Curtius, A. J. (2005). Determination of Trace Metals in Electrolytic Copper by ICP-OES and ICP-MS. Brazilian Archives of Biology and Technology, 48, 681-687.
Strausak, D., Mercer, J. F. B., Dieter, H. H., Stremmel, W. & Multhaup, G. (2001). Copper in Disorders with Neurological Symptoms: Alzheimer’s, Menkes, and Wilson diseases. Brain Research Bulletin, 55,
175-185.
Wang, J., Yang, Q., Song, H. & Zhang, W. (2012). A Fluorescent Probe of N′-formyl-rhodamine B Hydrazide: Structure and Spectral Properties of Protonation Behaviour. Organic & Biomolecular Chemistry, 10,
7677-7680.
Xiang, Y., Tong, A., Jin, P., Ju, Y. (2006). New Fluorescent Rhodamine Hydrazone Chemosensor for Cu(II) with High Selectivity and Sensitivity. Organic Letters, 8, 2863-2866.
Zhang, L.-Z. (2013). Conjugate Heat and Mass Transfer in Heat Mass Exchanger Ducts: Chapter 12 - Novel Materials for Heat and Mass Exchangers. Novel Materials for Heat and Mass Exchangers, 335-369.
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Published
2021-01-05
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