Corrosion Inhibition of Galvanized Steel in Hydrochloric Acid Solution using ¬¬ 1,8-Diazabicyclo[5.4.0]undec-7-ene as New Organic Inhibitor
Abstract
In this work, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) was, for the first time, utilized as the organic corrosion inhibitor for galvanized steel in 1.0 M HCl, at 30 oC and 40oC. The corrosion reactions of galvanized steel in 1.0 M HCl with DBU concentrations: 3.0, 6.0, 9.0 and 50.0 mM and without DBU had been investigated by gasometrical and weight loss measurements. The results from both techniques showed that DBU was found to be the highly effective corrosion inhibitor for galvanized steel in an acidic media. The highly inhibiting efficiency of DBU was up to 88% at 30oC. The result from kinetics study showed that the corrosion rate of steel was decreased with decreasing of temperature and increasing of DBU concentration. Moreover, the activation energy (Ea) was increased with increasing of DBU concentration. From thermodynamic analysis, the adsorption of DBU on steel surface was physical adsorption and spontaneous process, due to the free energy changes of adsorption are negative (∆G values are -14 to -27 kJ/mol). Overall results suggested that, in significant, the presence of DBU can effectively prevent the damage of steel sheet in HCl solution. Keywords : galvanized steel, corrosion, 1,8-diazabicyclo[5.4.0]undec-7-ene, adsorption, kineticsReferences
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Ansari, K.R., Quraishi, M.A. & Singh, A. (2014). Schiff’s Base of Pyridyl Substituted Triazoles As New and Effective Corrosion Inhibitors For Mild Steel in Hydrochloric Acid Solution. Corrosion Science, 79, 5-15.
Armstrong, R.D. & Peggs, L. (1994). The Behaviour of Lead Silicate As a Corrosion Inhibitor for Iron and Zinc, Corrosion Science, 36, 749-757.
Bayol, E., Kayakirilmaz, K. & Erbil, M. (2007). The Inhibitive Effect of Hexamethylenetetramine of The Acid Corrosion of Steel. Materials Chemistry and Physics, 104, 74-82.
Bentiss, F., Bouanis, M., Mernari, B., Traisnel, M., Vein, H. & Lagrenee, M. (2007). Understanding The Adsorption of 4H-1,2,4-Triazole Derivatives on Mild Steel Surface in Molar Hydrochloric Acid. Applied Surface Science, 253, 3696-3704.
Bhajiwala, H.M. & Vashi, R.T. (2001). Ethanolamine, Diethanolamine and Triethanolamine As Corrosion Inhibitors for Zinc in Binary Acid Mixture (HNO3 + H3PO4). Bulletin of Electrochemistry, 17, 441-448.
Donahue, F.M. & Nobe, K. (1965). Theory of Organic Corrosion Inhibitors: Adsorption and Linear Free Energy Relationships. Journal of Electrochemical Society, 112, 886-891.
Dove, A.P. (2012). Organic Catalysis for Ring-Opening Polymerization. ACS Macro Letters, 1, 1409-1412.
El-Etre, A.Y. (2006). Khillah Extract As Inhibitor for Acid Corrosion of SX 316 Steel. Applied Surface Science, 252, 8521-8525.
Kamis, E., Bellucci, F., Latanision, R.M. & El-Ashry, E.S.H. (1991). Acid Corrosion Inhibition of Nickel by
2-(Triphenosphoranylidene) Succinic Anhydride. Corrosion, 47, 677-686.
Kosari, A., Moayed, M. H., Davoodi, A., Parvizi, R., Momeni, M., Eshghi, H. & Moradi, H. (2014). Electrochemical And Quantum Chemical Assessment of Two Organic Compounds From Pyridine Derivatives As Corrosion Inhibitors for Mild Steel in HCl Solution Under Stagnant Condition and Hydrodynamic Flow. Corrosion Science, 78, 138-150.
Kwolek, P., Kaminski, A., Dychton, K., Drajewicz, M. & Sieniawski, J. (2016). The Corrosion Rate of Aluminium in The Orthophosphoric Acid Solutions in The Presence of Sodium Molybdate. Corrosion Science, 106,
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Liu, H., Gu, T. Zhang, G., Wang, W., Dong, S., Cheng, Y. & Liu, H. (2016). Corrosion Inhibition of Carbon Steel in CO2-Containg Oilfield Produced Water in The Presence of Iron-Oxidizing Bacteria and Inhibitors. Corrosion Science, 105, 149-160.
Mourya, P., Banerjee, S., Singh, M.M. (2014). Corrosion Inhibition of Mild Steel in Acidic Solution by Tageteserecta (Marigold flower) Extract As A Green Inhibitor. Corrosion Science, 85, 352-363.
O’MBockris, I. & Swinkles, D.A. (1964). Adsorption of n-Decylamine on Solid Metal Electrodes. Journal of Electrochemical Society, 111, 736-743.
Obot, I.B. & Obi-Egbedi, N.O. (2010) Theoretical Study of Benzimidazole and Its Derivatives and Their Potential Activity As Corrosion Inhibitors. Corrosion Science, 52, 657-660.
Oguzie, E.E. (2007). Corrosion Inhibition of Aluminum in Acidic and Alkaline Media by Sansevieriatrifasciata Extract. Corrosion Science, 49, 1527-1539.
Okafor, P.C., Ikpi, M.E., Uwah, I.E., Ebensi, E.E., Ekoe, U.J. & Umoren, S.A. (2008). Inhibition Action of Phyllanthusamarus Extracts on The Corrosion of Mile Steel in Acidic Media. Corrosion Science, 50,
2310-2317.
Roberge, P.R. (1999). Handbook of Corrosion Engineering. New York: McGraw-Hill.
Rudresh, H.B. & Mayanna, S.M. (1980). Tertiary Arsines As Corrosion Inhibitors for Zinc in Acid Solution. Materials and Corrosion, 31, 286-290.
Salarvand, Z., Amirnasr, M., Talebian, M., Raeissi, K. & Meghdadi, S. (2017). Enhanced Corrosion Resistance of Mild Steel in 1 M HCl Solution by Trace Amount of 2-Phenyl-benzothiazole Derivatives: Experimental, Quantum Chemical Calculation and Molecular Dynamics (MD) Simulation Studies. Corrosion Science, 114, 33-145.
Singh, A.K. & Quraishi, M.A. (2010). The Effect of Some Bis-thiadiazole Derivatives on The Corrosion of Mild Steel in Hydrochloric Acid. Corrosion Science, 52, 1373-1385.
Vashi, R.T., Bhajiwala, H.M. & Desai, S.A. (2010). Ethanolamines As Corrosion Inhibitors for Zinc in (HNO3 + H2SO4) Binary Acid Mixtures, E-Journal of Chemistry, 7, 665-668.
Zhang, K., Xy, B., Yang, W., Yin, X., Liu, Y. & Chen, Y. (2015). Halogen-Substituted Imidazoline Derivatives As Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution. Corrosion Science, 90, 284-295.
Ansari, K.R., Quraishi, M.A. & Singh, A. (2014). Schiff’s Base of Pyridyl Substituted Triazoles As New and Effective Corrosion Inhibitors For Mild Steel in Hydrochloric Acid Solution. Corrosion Science, 79, 5-15.
Armstrong, R.D. & Peggs, L. (1994). The Behaviour of Lead Silicate As a Corrosion Inhibitor for Iron and Zinc, Corrosion Science, 36, 749-757.
Bayol, E., Kayakirilmaz, K. & Erbil, M. (2007). The Inhibitive Effect of Hexamethylenetetramine of The Acid Corrosion of Steel. Materials Chemistry and Physics, 104, 74-82.
Bentiss, F., Bouanis, M., Mernari, B., Traisnel, M., Vein, H. & Lagrenee, M. (2007). Understanding The Adsorption of 4H-1,2,4-Triazole Derivatives on Mild Steel Surface in Molar Hydrochloric Acid. Applied Surface Science, 253, 3696-3704.
Bhajiwala, H.M. & Vashi, R.T. (2001). Ethanolamine, Diethanolamine and Triethanolamine As Corrosion Inhibitors for Zinc in Binary Acid Mixture (HNO3 + H3PO4). Bulletin of Electrochemistry, 17, 441-448.
Donahue, F.M. & Nobe, K. (1965). Theory of Organic Corrosion Inhibitors: Adsorption and Linear Free Energy Relationships. Journal of Electrochemical Society, 112, 886-891.
Dove, A.P. (2012). Organic Catalysis for Ring-Opening Polymerization. ACS Macro Letters, 1, 1409-1412.
El-Etre, A.Y. (2006). Khillah Extract As Inhibitor for Acid Corrosion of SX 316 Steel. Applied Surface Science, 252, 8521-8525.
Kamis, E., Bellucci, F., Latanision, R.M. & El-Ashry, E.S.H. (1991). Acid Corrosion Inhibition of Nickel by
2-(Triphenosphoranylidene) Succinic Anhydride. Corrosion, 47, 677-686.
Kosari, A., Moayed, M. H., Davoodi, A., Parvizi, R., Momeni, M., Eshghi, H. & Moradi, H. (2014). Electrochemical And Quantum Chemical Assessment of Two Organic Compounds From Pyridine Derivatives As Corrosion Inhibitors for Mild Steel in HCl Solution Under Stagnant Condition and Hydrodynamic Flow. Corrosion Science, 78, 138-150.
Kwolek, P., Kaminski, A., Dychton, K., Drajewicz, M. & Sieniawski, J. (2016). The Corrosion Rate of Aluminium in The Orthophosphoric Acid Solutions in The Presence of Sodium Molybdate. Corrosion Science, 106,
208-216.
Limwanich, W. & Witthayaprapakorn, C. (2016). Corrosion Protection of Zinc Sheet in Acidic Media Using D,L-Lactic Acid As Green Corrosion Inhibitor. Burapha Science Journal, 21(3), 249-256. (in Thai)
Liu, H., Gu, T. Zhang, G., Wang, W., Dong, S., Cheng, Y. & Liu, H. (2016). Corrosion Inhibition of Carbon Steel in CO2-Containg Oilfield Produced Water in The Presence of Iron-Oxidizing Bacteria and Inhibitors. Corrosion Science, 105, 149-160.
Mourya, P., Banerjee, S., Singh, M.M. (2014). Corrosion Inhibition of Mild Steel in Acidic Solution by Tageteserecta (Marigold flower) Extract As A Green Inhibitor. Corrosion Science, 85, 352-363.
O’MBockris, I. & Swinkles, D.A. (1964). Adsorption of n-Decylamine on Solid Metal Electrodes. Journal of Electrochemical Society, 111, 736-743.
Obot, I.B. & Obi-Egbedi, N.O. (2010) Theoretical Study of Benzimidazole and Its Derivatives and Their Potential Activity As Corrosion Inhibitors. Corrosion Science, 52, 657-660.
Oguzie, E.E. (2007). Corrosion Inhibition of Aluminum in Acidic and Alkaline Media by Sansevieriatrifasciata Extract. Corrosion Science, 49, 1527-1539.
Okafor, P.C., Ikpi, M.E., Uwah, I.E., Ebensi, E.E., Ekoe, U.J. & Umoren, S.A. (2008). Inhibition Action of Phyllanthusamarus Extracts on The Corrosion of Mile Steel in Acidic Media. Corrosion Science, 50,
2310-2317.
Roberge, P.R. (1999). Handbook of Corrosion Engineering. New York: McGraw-Hill.
Rudresh, H.B. & Mayanna, S.M. (1980). Tertiary Arsines As Corrosion Inhibitors for Zinc in Acid Solution. Materials and Corrosion, 31, 286-290.
Salarvand, Z., Amirnasr, M., Talebian, M., Raeissi, K. & Meghdadi, S. (2017). Enhanced Corrosion Resistance of Mild Steel in 1 M HCl Solution by Trace Amount of 2-Phenyl-benzothiazole Derivatives: Experimental, Quantum Chemical Calculation and Molecular Dynamics (MD) Simulation Studies. Corrosion Science, 114, 33-145.
Singh, A.K. & Quraishi, M.A. (2010). The Effect of Some Bis-thiadiazole Derivatives on The Corrosion of Mild Steel in Hydrochloric Acid. Corrosion Science, 52, 1373-1385.
Vashi, R.T., Bhajiwala, H.M. & Desai, S.A. (2010). Ethanolamines As Corrosion Inhibitors for Zinc in (HNO3 + H2SO4) Binary Acid Mixtures, E-Journal of Chemistry, 7, 665-668.
Zhang, K., Xy, B., Yang, W., Yin, X., Liu, Y. & Chen, Y. (2015). Halogen-Substituted Imidazoline Derivatives As Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution. Corrosion Science, 90, 284-295.
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2018-05-02
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