Investigation of Solvatochromic Effect in Fluorescence Dye Solutions
Abstract
In this research, we used different solvents with different polarity to demonstrate the change of fluorescence spectra of fluorescent dyes including Fluorescein, Bromofluorescein, Rhodamine 6G and Rhodamine B at fixed concentration (10-3 molar) by using laser induced fluorescence (LIF) technique. The 395 nm purple laser was used to excite fluorescent molecules at room temperature. The fluorescence spectra were detected by a spectrometer which was performed under a computer interfacing software. It was found from the experiment that each solvent have their own effect on fluorescence spectra which are results from the reaction between solvent and fluorescent dye solution. Keyword: Fluorescence, Solvent effect, Solvent polarity, Solvatochromic shiftReferences
Basavaraja, J., Inamdar, S.R.&Suresh, H.M.K. (2015). Solvents effect on the absorption and fluorescence
spectra of 7-diethylamino-3-thenoylcoumarin: Evaluation and correlation between solvatochromism
and solvent polarity parameters. Spectrochimica Acta Part A: Molecular and Biomolecular
Spectroscopy, 137, 527-534.
Benchea, A.C., Babusca, D., Morosanu, A.C., Dimitriu, D.G., & Dorohoi, D.O. (2017). Spectral study of Rhodamine dyes in binary solutions. Journal of Molecular Structure, 1140, 71–76.
Bruno, T.J & Svoronos, P.D.N. (2011). Handbook of Basic Tables for Chemical Analysis (3rd ed.) United states of America on acid-free paper: Taylor & Francis Group LLC.
Chakraborty, M. & Panda, K.A. (2011). Spectral behaviour of eosin Y in different solvents and aqueous surfactant media. Spectrochimica Acta Part A, 81, 458-465.
Ghini, G., et. al. (2013). Carbon nanotubes modified with fluorescein derivatives for pH nanosensing. Sensors and Actuators B, 179, 163– 169.
Guilbault, G. G. (1990). Practical Fluorescence (2nd ed.) New York: Marcel Dekker.
Lakowicz, J.R. (2006). Principles of Fluorescence Spectroscopy (3rd ed.) New York: SpringerScience+Business.
Mannekutla, J.R., Mulimani, B.G. & Inamdar Nag, S.R. (2008). Solvent effect on absorption and fluorescence spectra of coumarin laser dyes: Evaluation of ground and excited state dipole moments. Spectrochimica Acta Part A, 206, 419-426.
Naderi, F., Farajtabar, A. & Gharib, F. (2014).Solvatochromic and preferential solvation of fluorescein in some water-alcoholic mixed solvents. Journal of Molecular Liquids, 190, 126-132.
Nag, A. & Goswami, D. (2009). Solvent effect on two-photon absorption and fluorescence of rhodaminedyes. Journal of Photochemistry and Photobiology A: Chemistry, 206, 188-197.
Rauf, M..A. & Hisaindee, S. (2013). Studies on solvatochromic behavior of dyes using spectral techniques. Journal of Molecular Structure, 1042, 45–56.
Reichardt, C. (2003). Solvents and Solvent Effects in Organic Chemistry (3rd ed.) Weinheim: WILEY-VCH Verlag GmbH & Co.
Sharma, R., Joshi, S., Bhattacharjee, R. & Pant, D.D. (2015). Solvent effect on absorption and fluorescence spectra of cinchonine and cinchonidinedications: Estimation of ground and excited state dipole moments by experimental and numerical studies. Journal of Molecular Liquids, 206, 519-164.
Thipperudrappa, J., Biradar, D.S., Manohara, S.R., Hanagodimath, S.M., Inamadar, S.R. & Manekutla,R.J. (2008). Solvent effects on the absorption and fluorescence spectra of some laser dyes: Estimation of
ground and excited-state dipole moments. Spectrochimica Acta Part A, 69, 991-997.
Timberlake, K.C. (2004). Chemistry Structures of Life (Platinum ed.) San Francisco: Benjamin Cummings.
Yang, Y., Bin, L., & Liming, Z. (2013). Design and synthesis of triphenylamine-malonitrile derivatives as
solvatochromic fluorescent dyes. Sensors and Actuators B, 183, 46– 51.
Yeshchenko, O. A., Bondarchuk, I.S., Kozachenko, V.V. & Losytskyy M.Y. (2015). Photoluminescence of rhodamine 6G in plasmonic field of Au nanoparticles:Temperature effects. Journal of Luminescence, 158, 294–300.
spectra of 7-diethylamino-3-thenoylcoumarin: Evaluation and correlation between solvatochromism
and solvent polarity parameters. Spectrochimica Acta Part A: Molecular and Biomolecular
Spectroscopy, 137, 527-534.
Benchea, A.C., Babusca, D., Morosanu, A.C., Dimitriu, D.G., & Dorohoi, D.O. (2017). Spectral study of Rhodamine dyes in binary solutions. Journal of Molecular Structure, 1140, 71–76.
Bruno, T.J & Svoronos, P.D.N. (2011). Handbook of Basic Tables for Chemical Analysis (3rd ed.) United states of America on acid-free paper: Taylor & Francis Group LLC.
Chakraborty, M. & Panda, K.A. (2011). Spectral behaviour of eosin Y in different solvents and aqueous surfactant media. Spectrochimica Acta Part A, 81, 458-465.
Ghini, G., et. al. (2013). Carbon nanotubes modified with fluorescein derivatives for pH nanosensing. Sensors and Actuators B, 179, 163– 169.
Guilbault, G. G. (1990). Practical Fluorescence (2nd ed.) New York: Marcel Dekker.
Lakowicz, J.R. (2006). Principles of Fluorescence Spectroscopy (3rd ed.) New York: SpringerScience+Business.
Mannekutla, J.R., Mulimani, B.G. & Inamdar Nag, S.R. (2008). Solvent effect on absorption and fluorescence spectra of coumarin laser dyes: Evaluation of ground and excited state dipole moments. Spectrochimica Acta Part A, 206, 419-426.
Naderi, F., Farajtabar, A. & Gharib, F. (2014).Solvatochromic and preferential solvation of fluorescein in some water-alcoholic mixed solvents. Journal of Molecular Liquids, 190, 126-132.
Nag, A. & Goswami, D. (2009). Solvent effect on two-photon absorption and fluorescence of rhodaminedyes. Journal of Photochemistry and Photobiology A: Chemistry, 206, 188-197.
Rauf, M..A. & Hisaindee, S. (2013). Studies on solvatochromic behavior of dyes using spectral techniques. Journal of Molecular Structure, 1042, 45–56.
Reichardt, C. (2003). Solvents and Solvent Effects in Organic Chemistry (3rd ed.) Weinheim: WILEY-VCH Verlag GmbH & Co.
Sharma, R., Joshi, S., Bhattacharjee, R. & Pant, D.D. (2015). Solvent effect on absorption and fluorescence spectra of cinchonine and cinchonidinedications: Estimation of ground and excited state dipole moments by experimental and numerical studies. Journal of Molecular Liquids, 206, 519-164.
Thipperudrappa, J., Biradar, D.S., Manohara, S.R., Hanagodimath, S.M., Inamadar, S.R. & Manekutla,R.J. (2008). Solvent effects on the absorption and fluorescence spectra of some laser dyes: Estimation of
ground and excited-state dipole moments. Spectrochimica Acta Part A, 69, 991-997.
Timberlake, K.C. (2004). Chemistry Structures of Life (Platinum ed.) San Francisco: Benjamin Cummings.
Yang, Y., Bin, L., & Liming, Z. (2013). Design and synthesis of triphenylamine-malonitrile derivatives as
solvatochromic fluorescent dyes. Sensors and Actuators B, 183, 46– 51.
Yeshchenko, O. A., Bondarchuk, I.S., Kozachenko, V.V. & Losytskyy M.Y. (2015). Photoluminescence of rhodamine 6G in plasmonic field of Au nanoparticles:Temperature effects. Journal of Luminescence, 158, 294–300.
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2017-09-15
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บทความวิจัยจากการประชุมวิชาการระดับชาติ"วิทยาศาสตร์วิจัย"ครั้งที่ 9
