Utilization of Duck Eggshell Powder as Natural Adsorbent for the Removal of Acid and Basic Dye from Water
Abstract
Synthetic dyes have been widely used in various industries. The wastewater contaminated with such dyes are then released to surface water, resulting in water pollution and human health. Hence, the dye removal is required in order to prevent the problems caused by the contamination of synthetic dye in water. Duck eggshells are waste material, which can be easily obtained from restaurant and Thai dessert factory. In this work, duck eggshells were used as adsorbent for the removal of titan yellow (acid dye) and crystal violet (basic dye) in aqueous solution. The effects of the pH of dye solution, absorbent dosage and initial dye concentration on the adsorption were investigated. It was found that the adsorption percentages were 84-92% and 87-92% for the titan yellow solutions at pH 5-8 and the crystal violet solutions at pH 5 -10, respectively. Either the increase of adsorption dosage or the decrease of dye concentration decreased the adsorption ability at equilibrium. The adsorption kinetics of both dyes fit well to the pseudo-second-order model. The equilibrium adsorption amounts of titan yellow and crystal violet followed the Freundlich and Langmuir isotherms, respectively. Keywords : duck eggshell ; titan yellow ; crystal violet ; adsorption kinetics ; adsorption isothermReferences
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Cheruiyot, G. K., Wanyonyi, W. C., Kiplimo, J. J., & Maina, E. N. (2019). Adsorption of toxic crystal violet dye using coffee husks: Equilibrium, kinetics and thermodynamics study. Scientific African, 5, 116-126.
De Angelis, G., Medeghini, L., Conte, A. M., & Mignardi, S. (2017). Recycling of eggshell waste into low-cost
adsorbent for Ni removal from wastewater. Journal of Cleaner Production, 164, 1497-1506.
Habeeb, O. A., Yasin, F. M., & Danhassan, U. A. (2014). Characterization and application of chicken eggshell
as green adsorbents for removal of H2S from wastewaters. Journal of Environmental Science, Toxicology and Food Technology, 8(11), 7-12.
Lellis, B., Fávaro-Polonio, C. Z., Pamphile, J. A., & Polonio, J. C. (2019). Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnology Research and Innovation, 3, 275-290.
Mittal, A., Teotia, M., Soni, R. K., & Mittal, J. (2016). Applications of eggshell and eggshell membrane as adsorbents: A review. Journal of Molecular Liquids, 223, 376-387.
Ngadi, N., & Jusoh, W. N. S. W. (2013). Removal of ethyl orange dye using waste eggshell. Journal Teknologi, 64(1), 101-107.
Shakeri, S., Rafiee, Z., & Dashtian, K. (2020). Fe3O4‑Based Melamine-Rich Covalent Organic Polymer for simultaneous removal of Auramine O and Rhodamine B. Journal of Chemical & Engineering Data, 65, 696–705.
Shi, Q. X., Li, Y., Wang, L., Wang, J., & Cao, Y. L. (2020). Preparation of supported chitosan adsorbent
with high adsorption capacity for Titan Yellow removal. International Journal of Biological Macromolecules, 152, 449-455.
Tsai, W. T., Yang, J. M., Lai, C. W., Cheng, Y. H., Lin, C. C., & Yeh, C. W. (2006). Characterization and
adsorption properties of eggshells and eggshell membrane. Bioresource Technology, 97(3), 488-493.
Weisburger, J.H. (2002). Comments on the history and importance of aromatic and heterocyclicamines in public health. Mutation Research Fundamental of Molecular Mechanics and Mutagenesis, 506-507,
9-20.
Zhou, L., Zhou, H., Hu, Y., Yan, S., & Yang, J. (2019). Adsorption removal of cationic dyes from aqueous solutions using ceramic adsorbents prepared from industrial waste coal gangue. Journal of environmental management, 234, 245-252.
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Published
2021-05-05
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