Removal of Toxic Heavy Metals in Water by Using Natural Products as Adsorbent
Abstract
The objective of this work was to investigate the bract, stem, midrib, and banana peel of cultivated banana as an adsorbent for the removal of five heavy metals which are Pb(II), Ni(II), Cu(II), Mn(II), and Zn(II) from synthetic wastewater. The adsorption factors studied were the contact time, concentration of solutions and pH. Moreover, we also compared the adsorption processes based on the Langmuir and Freundlish isotherms. The adsorption efficiency in 10 mg/L of heavy metals were found, from high to low efficiencies as follow: banana peel (91.50 – 98.43%), bract (82.77 – 96.80%), stem (77.40 – 96.73%), and midrib (67.77 – 98.03%), respectively. The adsorption capacity of M(II) ions on the adsorbents were proportional to the initial concentration of solutions. From this work, the adsorbents can be used to adsorb all kinds of these heavy metal ions, therefore, they might be applied for another wastewater treatment Keywords : heavy metal, adsorption, banana treeReferences
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trioctahedral smectites: A comparative study of the effectiveness on the heavy metal adsorption from
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BADGE (Bisphenol A Diglycidyl Ether) through Reflux Method. International Journal of Environmental
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aquatic plants in heavy metal-polluted Water. International Journal of Environmental Research and
Public Health, 12, 14958 – 14973.
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Suranaree University of Technology. (in Thai).
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Al-Si-O bearing mineral system: Insights from theory and experiments. Separation and Purification
Technology, 186, 28 – 38.
Singthuan, P. (2015). Thesis : Effect of copper on the treatment of oxytetracycline contaminated water by
narrow-leaved cat-tail (Typna angustifolia L.). Bangkok: Silpakorn University. (in Thai).
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Umpuch, C., Namduang, P., & Yawong, P. (2017). Adsorption of cadmium from aqueous solutions by pomelo
peel (Citrus grandis). Journal of science and technology, 19(1), 138 – 151. (in Thai).
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Wang, F., Pan, Y., Cai, P., Guo, T., & Xiao, H. (2017). Single and binary adsorption of heavy metal ions from
aqueous solutions using sugarcane cellulose-based adsorbent. Bioresource Technology, 241, 482 – 490.
Wikipedia. (2017). Banana. Retrived February 15, 2017, from http://www.th.wikipedia.org/wiki/banana. (in Thai).
Narathiwat province. Narathiwat: Princess of Naradhiwas University. (in Thai).
Chaibu, P., & Chawanchai, B. (2007). Use of longan peel as an adsorbent for metal ion(cadmium and lead)
adsorbtion in aqueous solution. In Proceedings of 45th Kasetsart University Annual Conference:
Architecture and Engineering and Natural Resources and Environment. (pp. 858 – 866). Thailand.
Kasetsart University. (in Thai).
Dana, E. (2017). Adsorption of heavy metals on functionalized-mesoporous silica: A review. Microporous and
Mesoporous Material, 247, 145 – 157.
Deng, P.Y., Liu, W., Zeng, B.Q., Qiu, Y.K., & Li, L.S. (2013). Sorption of heavy metals from aqueous solution by
dehydrated powders of aquatic plants. International Journal of Environment Science and Technology,
10, 559 – 566.
Dokbua, J., Phasuk, S., & Tundulawessa, Y. (2008). Effectciency of cellulose phosphate from straw and bagasse
for adsoerption lead and cadmium in waste water. Journal of graduate studies valaya alongkron rajabhat university, 2, 1 – 8. (in Thai)
Dubey, A., & Shiwani, S. (2012). Adsorption of lead using a new green material obtained from Portulaca plant.
International Journal of Environmental Science and Technology, 9, 15 – 20.
Dupont M, F., Gloaguen, V., Guilloton, M., Granet, R., & Krausz, P. (2006). Study of the chemical interaction
between barks and heavy metal cations in the sorption process. Journal of Environmental Science and Health – Part A Toxic/Hazardous Substances and Environmental Engineering, 41(2), 149 – 60.
Franco, F., Benítez-Guerrero, M., Gonzalez-Trivino, I., Perez-Recuerda, R., Assiego, C., Cifuentes-Melchor, J.,
& Pascual-Cosp, J. (2016). Low-cost aluminum and iron oxides supported on dioctahedral and
trioctahedral smectites: A comparative study of the effectiveness on the heavy metal adsorption from
water. Applied Clay Science, 119, 321 – 332.
Hastuti, B., Mudasir, D., Siswanta., & Triyono. (2015). Biosorption of Pb(II) Ion by Crosslinked Pectin-CMC with
BADGE (Bisphenol A Diglycidyl Ether) through Reflux Method. International Journal of Environmental
Science and Development, 6, 77 – 82.
Kerdcry, S., & chaninmanu, S. (2004). Report - Heavy metal toxicity. Phayao: Phayao provincial public health
office. (in Thai).
Kumtabtim, U., & Siripinyanon, A. (2017). Study of remove ability for heavy metals in waste water by using applied
Cassava leaves. Science and Technology RMUTT Journal, 6(2), 37 – 47. (in Thai).
Li, J., Yu, H., & Luan, Y. (2015). Meta-analysis of the copper, zinc, and cadmium absorption capacities of
aquatic plants in heavy metal-polluted Water. International Journal of Environmental Research and
Public Health, 12, 14958 – 14973.
Lina, S., Lianb, C., Xua, M., Zhanga, W., Liua, L., & Lin, K. (2017). Study on competitive adsorption mechanism
among oxyacid-type heavy metals in co-existing system: Removal of aqueous As(V), Cr(III) and As(III)
using magnetic iron oxide nanoparticles (MIONPs) as adsorbents. Applied Surface Science, 422,
675 – 681.
Nambang, W. (2014). Report - Distribution of heavy metals in rice field around the landfill pond (case study of
tumbon Wangnumkoo, Muang, Phitsanulok). Phitsanulok: Naresuan university. (in Thai).
Narawong, W. & Panya, P. (2017). Preparation of Cellulose from Water Hyacinth Leave to Adsorb Cr (VI) Ion. In
Proceedings of 4rd Research institute of Kamphaeng Phet Rajabhat University annual conference.
(pp. 957 – 966). Thailand. Kamphaeng Phet Rajabhat University. (in Thai).
Pengpean, W., Wongtanet, J., Junanurat, A., & Sornsuwan, P. (2013). Perfomance of typical adsorbent for lead in
waste water. Journal of environmental health, 15(3), 29 – 37. (in Thai)
Phaphromphuek, P. (2016). Adsorption and waste water treatment. MSU research digest, 3, 51 – 57. (in Thai).
Peng, W., Li, H., Liu, Y., & Song, S. (2016). A review on heavy metal ions adsorption from water by graphene
oxide and its composites. Journal of Molecular Liquids, 230, 496 – 504.
Phalathip, P. (2016). Thesis - the adsorption of heavy metal using modified synthetic fiber. Nakhon Ratchasima:
Suranaree University of Technology. (in Thai).
Pintawong, J., Nontaso, A., & Kawinate, S. (2011). Report - Management to approach of manganese mineral for
fiscal year 2011. Bangkok: Department of mineral resoures. (in Thai).
Pollution control department. (2017). Report of Thailand’s pollution situation : water quality in each region.
Bangkok. Ministry of Natural Resources and Environment. (in Thai).
Ramkul, P. (2010). Innovation of tannin adsorbent for removing metal from solution. Kasetsart Engineering
Journal, 72, 17 – 29. (in Thai).
Rath, S.S., Singh, S., Rao, D.S., Nayak, B.B., & Mishra, B.K. (2017). Adsorption of heavy metals on a complex
Al-Si-O bearing mineral system: Insights from theory and experiments. Separation and Purification
Technology, 186, 28 – 38.
Singthuan, P. (2015). Thesis : Effect of copper on the treatment of oxytetracycline contaminated water by
narrow-leaved cat-tail (Typna angustifolia L.). Bangkok: Silpakorn University. (in Thai).
Seangsesot, S. (2000). Banana: high benefit fruit. Departmaent of science service journal,153, 3 – 5. (in Thai).
TK park. (2017). Handbook of activity model for banana’s topic. Bangkok: Thai Health Promotion Foundation.
(in Thai).
Umpuch, C., Namduang, P., & Yawong, P. (2017). Adsorption of cadmium from aqueous solutions by pomelo
peel (Citrus grandis). Journal of science and technology, 19(1), 138 – 151. (in Thai).
Usanawarong, S. (2006). Zinc and high blood pressure. Journal of community service, 2, 23 – 28. (in Thai).
Wang, F., Pan, Y., Cai, P., Guo, T., & Xiao, H. (2017). Single and binary adsorption of heavy metal ions from
aqueous solutions using sugarcane cellulose-based adsorbent. Bioresource Technology, 241, 482 – 490.
Wikipedia. (2017). Banana. Retrived February 15, 2017, from http://www.th.wikipedia.org/wiki/banana. (in Thai).
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Published
2019-05-23
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