Fabrication of Plasticized Polymer Membrane for Silver Ion Selective Electrode Using Anthraquinone Derivative as an Ionophore
Abstract
The fabrication of silver ion selective electrode (Ag-ISE) was carried out using polyvinyl chloride (PVC) membrane having anthraquinone derivative, L1, as ionophore, DOS as plasticizer and KTpClPB as ionic additive in 25, 50 and 75 mol% (relative to L1). The polymeric membrane electrode showed high response to Ag+ compared to other cations (Na+, K+, Mg2+, Ca2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+ and Pb2+). The selectivity coefficients () of the polymeric membrane electrodes were determined by separate solution method (SSM), and the results showed that other metal ions, except Cu2+ and Hg2+, had significantly lower selectivity coefficients than that of Ag+. The optimized membrane electrode exhibited near theoretical Nernstian slope of 55.41 ± 0.6 mV decade-1 with a linear working range from 1.0 x 10-5 to 1.0 x 10-2 mol L-1 and a detection limit of 8.74 x 10-7 mol L-1. Keywords : polymeric membrane electrode, ionophore, plasticizer, silver ionReferences
Abbaspour, A., Izadyar, A., Sharghi, H. (2004). Carbon Composition PVC based Membrane in a Highly Selective and Sensitive Coated Wire Electrode for Silver Ion. Analytica Chimica Acta, 525, 91–96.
Abu-Shawish, H. M., Saadeh, S. M., Dalloul, H. M., Najri, B., Al Athamna, H. (2013). Modified Carbon Paste Electrode for Potentiometric Determination of Silver(I) Ions in Burning Cream and Radiological Films. Sensors and Actuators B, 182, 374–381.
Bakker, E., Bühlmann, E., Pretsch, E. (1997). Carrier-based Ion-selective Electrodes and Bulk Optodes. 1. General Characteristics. Chemical Reviews, 97, 3083–3132.
Bobacka, J., Lahtinen, T., Koskinen, H., Rissanen, K., Lewenstam, A., Ivaska, A. (2002). Silver Ion-selective Electrodes Based on -Coordinating Ionophores without Heteroatoms. Electroanalysis, 14, 1353–1357.
Cattrall, R. W. (1997). Chemical Sensors. New York: Oxford Science Publications.
EPA (Environmental Protection Agency). (1989). EPA 7440-7422-7444. Office of Water Regulations, Washington. DC.
Eugster, E., Morf, P. M., Spichiger, U., Simon, W. (1991). Selectivity-modifying Influence of Anionic Sites in Neutral Carrier-based Membrane Electrodes. Analytical Chemistry, 63, 2285–2289.
Kazuyuki, M., Nobuo, H., Takatoshi, K., Yuriko, K., Osamu, H., Yashihisa, I., Kiyoko, S. (2001). Sensitive Method for Detection and Semiquantification of Bence Jones Protein by Cellulose Acetate Membrane Electrophoresis using Colloidal Silver Staining. Clinical Chemistry, 47, 763–766.
Kimura, K., Yajima, S., Tatsumi, K., Yokoyama, M., Oue, M. (2000). Silver Ion-selective Electrodes using -Coordinate Calix[4]arene Derivatives as Soft Neutral Carriers. Analytical Chemistry, 72, 5290–5294.
Lai, C. -Z., Fierke, M. A., Costa, R. C., Gladysz, J. A., Stein, A., Bühlmann, P. (2010). Highly Selective Detection of Silver in the Low ppt Range with Ion-selective Electrodes based on Ionophore-doped Fluorous Membranes. Analytical Chemistry, 82, 7634–7640.
Mittal, S. K., Kumar, A. S. K., Kaur, S., Kumar, S. (2007). Potentiometric Performance of 2-Aminothiophenol based Dipodal Ionophore as a Silver Sensing Material. Sensors and Actuators B, 121, 386–395.
Mittal, S. K., Kumar, P., Kumar S K, A., Lindoy, L. F. (2010). A Comparative Study of Linked 2,2’-Dipyridylamine Ligand System as an Ion Selective Electrode for Ag (I) Ions. International Journal of Electrochemical Science, 5, 1984–1995.
Mousavi, Z., Bobacka, J., Lewenstam, A., Ivaska, A. (2006). Response Mechanism of Potentiometric Ag+ Sensor based on Poly(3,4-ethylenedioxythiophene) Doped with Silver Hexabromocarborane. Journal of Electroanalytical Chemistry, 593, 219–226.
Ngeontae, W., Janrungroatsakul, W., Morakot, N., Aeungmaitrepirom, W., Tuntulani. T. (2008). New Silver Selective Electrode Fabricated from Benzothiazole Calix[4]arene: Speciation Analysis of Silver Nanoparticles. Sensors and Actuators B, 134, 377–385.
Rosatzin, T., Bakker, E., Suzuki, K., Simon, W. (1993). Lipophilic and Immobilized Anionic Additive in Solvent Polymeric Membranes of Cation Selective. Analytica Chimica Acta, 280, 197–203.
Thongkum, D., Punaray, J., Sanguankul, W., Ratchakom, V., Kumplong, P. (2015). Alkylamine Anthraquinone Chemical Sensors to Detect Nickel and Copper Ions. Srinakharinwirot Science Journal, 31(1), 51–64. (in thai)
Umezawa, Y., Bühlmann, K., Umezawa, K., Tohda, K., Amemiya, S. (2000). Potentiometric Selectivity Coefficients of Ion-selective Electrodes. Pure and Applied Chemistry, 72, 1851–2082.
Abu-Shawish, H. M., Saadeh, S. M., Dalloul, H. M., Najri, B., Al Athamna, H. (2013). Modified Carbon Paste Electrode for Potentiometric Determination of Silver(I) Ions in Burning Cream and Radiological Films. Sensors and Actuators B, 182, 374–381.
Bakker, E., Bühlmann, E., Pretsch, E. (1997). Carrier-based Ion-selective Electrodes and Bulk Optodes. 1. General Characteristics. Chemical Reviews, 97, 3083–3132.
Bobacka, J., Lahtinen, T., Koskinen, H., Rissanen, K., Lewenstam, A., Ivaska, A. (2002). Silver Ion-selective Electrodes Based on -Coordinating Ionophores without Heteroatoms. Electroanalysis, 14, 1353–1357.
Cattrall, R. W. (1997). Chemical Sensors. New York: Oxford Science Publications.
EPA (Environmental Protection Agency). (1989). EPA 7440-7422-7444. Office of Water Regulations, Washington. DC.
Eugster, E., Morf, P. M., Spichiger, U., Simon, W. (1991). Selectivity-modifying Influence of Anionic Sites in Neutral Carrier-based Membrane Electrodes. Analytical Chemistry, 63, 2285–2289.
Kazuyuki, M., Nobuo, H., Takatoshi, K., Yuriko, K., Osamu, H., Yashihisa, I., Kiyoko, S. (2001). Sensitive Method for Detection and Semiquantification of Bence Jones Protein by Cellulose Acetate Membrane Electrophoresis using Colloidal Silver Staining. Clinical Chemistry, 47, 763–766.
Kimura, K., Yajima, S., Tatsumi, K., Yokoyama, M., Oue, M. (2000). Silver Ion-selective Electrodes using -Coordinate Calix[4]arene Derivatives as Soft Neutral Carriers. Analytical Chemistry, 72, 5290–5294.
Lai, C. -Z., Fierke, M. A., Costa, R. C., Gladysz, J. A., Stein, A., Bühlmann, P. (2010). Highly Selective Detection of Silver in the Low ppt Range with Ion-selective Electrodes based on Ionophore-doped Fluorous Membranes. Analytical Chemistry, 82, 7634–7640.
Mittal, S. K., Kumar, A. S. K., Kaur, S., Kumar, S. (2007). Potentiometric Performance of 2-Aminothiophenol based Dipodal Ionophore as a Silver Sensing Material. Sensors and Actuators B, 121, 386–395.
Mittal, S. K., Kumar, P., Kumar S K, A., Lindoy, L. F. (2010). A Comparative Study of Linked 2,2’-Dipyridylamine Ligand System as an Ion Selective Electrode for Ag (I) Ions. International Journal of Electrochemical Science, 5, 1984–1995.
Mousavi, Z., Bobacka, J., Lewenstam, A., Ivaska, A. (2006). Response Mechanism of Potentiometric Ag+ Sensor based on Poly(3,4-ethylenedioxythiophene) Doped with Silver Hexabromocarborane. Journal of Electroanalytical Chemistry, 593, 219–226.
Ngeontae, W., Janrungroatsakul, W., Morakot, N., Aeungmaitrepirom, W., Tuntulani. T. (2008). New Silver Selective Electrode Fabricated from Benzothiazole Calix[4]arene: Speciation Analysis of Silver Nanoparticles. Sensors and Actuators B, 134, 377–385.
Rosatzin, T., Bakker, E., Suzuki, K., Simon, W. (1993). Lipophilic and Immobilized Anionic Additive in Solvent Polymeric Membranes of Cation Selective. Analytica Chimica Acta, 280, 197–203.
Thongkum, D., Punaray, J., Sanguankul, W., Ratchakom, V., Kumplong, P. (2015). Alkylamine Anthraquinone Chemical Sensors to Detect Nickel and Copper Ions. Srinakharinwirot Science Journal, 31(1), 51–64. (in thai)
Umezawa, Y., Bühlmann, K., Umezawa, K., Tohda, K., Amemiya, S. (2000). Potentiometric Selectivity Coefficients of Ion-selective Electrodes. Pure and Applied Chemistry, 72, 1851–2082.
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2016-07-06
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